Nickel-catalyzed addition of P(O)-H bonds to propargyl alcohols: one-pot generation of phosphinoyl 1,3-butadienes |
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| Authors: | Han Li-Biao Ono Yutaka Yazawa Hideaki |
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| Affiliation: | National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki, Japan. libiao-han@aist.go.jp |
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| Abstract: | [reaction: see text] Diphenylphosphine oxide and related P(O)H compounds react with propargyl alcohols at room temperature in the presence of a catalytic amount of Ni(0) complex and Ph(2)P(O)OH to produce high yields of phosphinoyl 1,3-dienes though an efficient in situ dehydration process. |
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