Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride |
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| Authors: | Rafii Esfandiar Dassonneville Benjamin Heumann Andreas |
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| Institution: | Université Paul Cézanne, UMR CNRS 6180 Chirotechnologies: Catalyse et Biocatalyse, Faculté Saint-Jér?me, Case A 62, 13397 Marseille Cedex 20, France. |
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| Abstract: | In non-racemic (1R,2R)-(1,2-dialkyl)-1,2-diaminocyclohexane palladium dichloride complexes the C2 symmetry of the diamine ligand is broken, resulting in selective R,S-coordination. |
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