High-temperature transnitrilation of 2-bromocaproic acid |
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| Authors: | Yu. N. Polivin V. A. Vinokurov S. V. Makarshin R. A. Karakhanov M. A. Silin E. A. Ageev |
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| Affiliation: | (1) Institute for Problems in Petroleum and Gas, Academy of Sciences of the USSR, Moscow;(2) I. M. Gubkin Moscow Institute of Petroleum and Gas, Moscow |
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| Abstract: | Chromato-mass spectrometry and IR and PMR spectroscopy were used to study the high-temperature reaction of 2-bromocaproic, 2-iodocaproic, and 2-bromo-2-phenylacetic acids with acetonitrile. The formation of anomalous transnitrilation products (capronitrile and benzyl cyanide) is a consequence of the initial conversion of 2-halo-substituted caproic and phenylacetic acids to caproic and phenylacetic acids, respectively.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1682–1684, July, 1990. |
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