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A model for two-electron mixed valence in metal-metal bonded dirhodium compounds |
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| Authors: | Gray Thomas G Nocera Daniel G |
| Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, 6-335, 77 Massachusetts Avenue, Cambridge, Massachusetts, USA. |
| Abstract: | We propose that two-electron mixed valency in bimetallic complexes possessing three bridging ligands results from a second-order Jahn-Teller instability of the redox-symmetric state. |
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