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Magnetic properties of the ferrimagnetic cobaltite CaBaCo4O7
Authors:Zhe Qu  Langsheng Ling  Li Pi  Yuheng Zhang
Institution:
  • a High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei, Anhui, 230031, China
  • b Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026, China
  • Abstract:The magnetic properties of the ferrimagnetic cobaltite CaBaCo4O7 are systematically investigated. We find that the susceptibility exhibits a downward deviation below ∼360 K, suggesting the occurrence of short-range magnetic correlations at a temperature well above TC. The effective moment is determined to be View the MathML source., which is consistent with that expected for the Co2+/Co3+ high spin species. Using a criterion given by Banerjee Phys. Lett. 12 (1964) 16], we demonstrate that the paramagnetic to ferrimagnetic transition in CaBaCo4O7 has a first order character.
    Keywords:A  Magnetically ordered materials  D  Phase transitions
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