Affiliation: | a NTT Basic Research Laboratories, NTT Corporation, 3-1 Morinosato-Wakamiya, Atsugi-shi, Kanagawa 243-0198, Japanb Department of Applied Physics, Tokyo University of Agriculture and Technology, Naka-cho 2-24-16, Koganei, Tokyo 184-8588, Japan |
Abstract: | Recent reports on superconductivity in parent compounds [RE = Pr, Nd, Sm, Eu, Gd] prepared by metal-organic decomposition (MOD) shed new light on the electronic and magnetic phase diagram of electron-doped cuprates. A thorough reduction process is the key to inducing superconductivity in square-planar coordinated cuprates. In this work, Pr2CuO4 films were grown epitaxially by molecular beam epitaxy (MBE) on (001)SrTiO3, (110)GdScO3 and (110)DyScO3 substrates. A modified two-step reduction process is required in order to obtain single-phase superconducting samples. The optimized superconducting properties are , while the room-temperature resistivity is about . Hence, we show that even amorphous Pr2CuOy films deposited on (110)DyScO3 become superconducting after the application of the two-step annealing process. These results indicate that superconductivity is induced to Pr2CuO4 by systematic optimization of the reduction conditions, irrespective of the synthesis route. |