| 苯丙烯酸衍生物的热力学特性研究 |
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| 引用本文： | 黄为钧,陈素明,谈夫,杨祯祥.苯丙烯酸衍生物的热力学特性研究[J].物理化学学报,1994,10(2):151-153. |
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| 作者姓名： | 黄为钧 陈素明 谈夫 杨祯祥 |
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| 作者单位： | Institute of Chemistry, Academia Sinica, Beijing 100080, Division of Medicinal Chemistry, China Pharmaceutical University |
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| 摘 要： | 激光染料分子——香豆素系列化合物【‘－‘1，8一经甲基香豆素衍生物【‘，’1的相变温度和相变偿分别与其母体7一位、6一位取代基团特性有着相互依赖关系．本文采用DSC法研究了2、3和4一甲氧基苯丙烯酸及个经基一3一甲氧基苯丙烯酸防们分别简称为1、D、m和w）在升温过程中的相变热力学特性，并对它们的结构与其热力学参数之间的关系进行了简要地分析．苯丙烯酸1、H、m和w的结构上。下：1实验部分1．1试样来源合成得到的试样，经鉴定其结构与分子式相符，并经元素分析测定，测定值与理论值相一致，表明试样具有较高纯度．1．2实验方法P…
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| 关 键 词： | 苯丙烯酸衍生物 差示扫描量热法 阿魏酸 熔化焓 |
| 收稿时间： | 1992-06-08 |
| 修稿时间： | 1992-10-07 |
Study on Thermodynamic Characteristics of Cinnamic Acid Derivatives |
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| Huang Weijun, Chen Suming, Tan Fu.Study on Thermodynamic Characteristics of Cinnamic Acid Derivatives[J].Acta Physico-Chimica Sinica,1994,10(2):151-153. |
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| Authors: | Huang Weijun Chen Suming Tan Fu |
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| Institution: | Institute of Chemistry, Academia Sinica, Beijing 100080| Division of Medicinal Chemistry, China Pharmaceutical University |
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| Abstract: | The phase transitions of 2-methoxycinnamic acid, 3-methoxycinnamic acid, 4-methoxycinnamic acid and 4-hydroxy-3-methoxycinnamic acid were studied by DSC. The thermodynamic parameters of phase transitions for these compounds are reported in this paper. In addition, the ~1H-NMR spectra of compounds 2-methoxycinnamic acid, 3-methoxycinnamic acid and 4-methoxycinnamic acid have been measured, and the change of β-H chemical shifts is consitent with that of DSC data fOr these compounds. |
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| Keywords: | Cinnamic acid derivative DSC(Differential Scanning Calorimetry) Ferulic acid Enthalpy of fusion |
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