Intramolecular aldol condensation of Michael adducts of levoglucosenone and cyclododecanone |
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| Affiliation: | Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences, 450054 Ufa, Russian Federation |
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| Abstract: | Base-promoted intramolecular aldol condensation of diastereomeric Michael adducts of levoglucosenone and cyclododecanone affords 12-hydroxy-14,20-dioxatetra-cyclo[9.6.1.112,17.113,16]icosan-18-one as a mixture of three diastereomers. The products thus obtained are promising for synthesizing 14-membered macrocyclic compounds, including cembranoids and their analogues. |
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