New access to azido-substituted alkylnitramines |
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| Institution: | N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
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| Abstract: | A new versatile access to azido-substituted N-alkylnitramines is based on ring opening in N-nitrooxazolidines and N-nitroperhydro-1,3-oxazines with thionyl chloride followed by treatment with sodium azide. Representative N,N-bis(azidoalkyl)- and N-azidoalkyl-N-methoxymethyl- containing nitramines were synthesized and characterized. |
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| Keywords: | nitramine azides thionyl chloride chlorination α μ-dichloro-2-nitro- 2-azaalkanes azidation phase transfer catalyst |
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