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The synthesis and copolymerization of 4-hydroxybenzylglycolide: experimental and theoretical aspects |
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| Affiliation: | 1. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;2. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
| Abstract: | Based on tyrosine, 4-hydroxybenzylglycolide was synthesized. Its study in ring-opening copolymerization with lactides in view of the ability of the phenolic hydroxy group to initiate polymerization was performed experimentally and with DFT modeling. |
| Keywords: | coordination catalysis functionalization glycolides lactides organocatalysis polyesters phenols ring-opening poly-merization |
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