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STUDY ON LOW Ni CATALYST FOR METHANATION OF TOWN GAS
摘    要:On the basis of the characterization of typical catalysts by activityevaluation,TPR,XRD and TEM,the effects of nickel content and promoterssuch as MgO,La_2O_3,and MnO_2 were discussed.Formation of MgNiO_2 by thecombination of promoter MgO with NiO increases the catalyst stability.Promot-er La_2O_3 is found well-distributed on the catalyst surface in the form of La_2O_3without any interaction with uther components.With physically scattering ef-fect,La_2O_3 can prohibit active component Ni from sintreing at high temperatureand then improve its thermal stability.It also affects the catalyst activity andreducibility.Introduction of La_2O_3 decreases the content of small Ni crystallite,and is helpful to the prohibition of carbon deposition.A new Ni-based town gasmethanation catalyst of low Ni content with high activity and high carbon depo-sition resistance is successfully developed in the laboratory.

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