Unprecedented migration of a methyl group in 2-(2',6'-dimethylphenylazo)-4-methylphenol mediated by ruthenium |
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Authors: | Nag Sumon Gupta Parna Butcher Ray J Bhattacharya Samaresh |
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Affiliation: | Department of Chemistry, Inorganic Chemistry Section, Jadavpur University, Kolkata 700 032, India. |
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Abstract: | An unprecedented chemical transformation of 2-(2',6'-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [Ru(PPh(3))(2)(CO)(2)Cl(2)] whereby the methyl group at the 2' position migrates to the 4' or 6' position. |
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