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Unprecedented migration of a methyl group in 2-(2',6'-dimethylphenylazo)-4-methylphenol mediated by ruthenium
Authors:Nag Sumon  Gupta Parna  Butcher Ray J  Bhattacharya Samaresh
Affiliation:Department of Chemistry, Inorganic Chemistry Section, Jadavpur University, Kolkata 700 032, India.
Abstract:An unprecedented chemical transformation of 2-(2',6'-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [Ru(PPh(3))(2)(CO)(2)Cl(2)] whereby the methyl group at the 2' position migrates to the 4' or 6' position.
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