| 应用于白光显示的Tm3+/Ho3+/Yb3+共掺碲酸盐玻璃上转换发光特性研究 |
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| 引用本文： | 王大刚,周亚训,王训四,戴世勋,沈祥,陈飞飞,王森. 应用于白光显示的Tm3+/Ho3+/Yb3+共掺碲酸盐玻璃上转换发光特性研究[J]. 物理学报, 2010, 59(9): 6256-6260 |
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| 作者姓名： | 王大刚 周亚训 王训四 戴世勋 沈祥 陈飞飞 王森 |
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| 作者单位： | 宁波大学信息科学与工程学院,宁波 315211 |
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| 基金项目： | 浙江省自然科学基金(批准号: Y107070),宁波市自然科学基金(批准号: 2010A610172),宁波大学学生SRIP项目,宁波大学研究生创新基金和宁波大学王宽诚幸福基金资助的课题. |
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| 摘 要： | 用高温熔融法制备了Tm3+/Ho3+/Yb3+共掺碲酸盐玻璃(TeO2-ZnO-La2O3)样品,测试了玻璃样品的吸收光谱和上转换发光光谱,分析了上转换发光机理.结果发现:在975 nm波长激光二极管(LD)激励下,制备的碲酸盐玻璃样品可以观察到强烈的红光(662 nm)、绿光(546 nm)和蓝光(480 nm)三基色上转换发光,红光对应于Tm3+离子关键词：碲酸盐玻璃上转换发光白光3+/Ho3+/Yb3+共掺')" href="#">Tm3+/Ho3+/Yb3+共掺
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| 关 键 词： | 碲酸盐玻璃 上转换发光 白光 Tm3+/Ho3+/Yb3+共掺 |
| 收稿时间： | 2009-12-21 |
Upconversion luminescence of Tm3+/Ho3+/Yb3+ codoped tellurite glass used for white light emission |
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| Wang Da-Gang,Zhou Ya-Xun,Wang Xun-Si,Dai Shi-Xun,Shen Xiang,Chen Fei-Fei,Wang Sen. Upconversion luminescence of Tm3+/Ho3+/Yb3+ codoped tellurite glass used for white light emission[J]. Acta Physica Sinica, 2010, 59(9): 6256-6260 |
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| Authors: | Wang Da-Gang Zhou Ya-Xun Wang Xun-Si Dai Shi-Xun Shen Xiang Chen Fei-Fei Wang Sen |
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| Affiliation: | College of Information Science and Engineering, Ningbo University, Ningbo 315211, China;College of Information Science and Engineering, Ningbo University, Ningbo 315211, China;College of Information Science and Engineering, Ningbo University, Ningbo 315211, China;College of Information Science and Engineering, Ningbo University, Ningbo 315211, China;College of Information Science and Engineering, Ningbo University, Ningbo 315211, China;College of Information Science and Engineering, Ningbo University, Ningbo 315211, China;College of Information Science and Engineering, Ningbo University, Ningbo 315211, China |
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| Abstract: | Tm3+/Ho3+/Yb3+ codoped tellurite glass (TeO2-ZnO-La2O3) was prepared by conventional melt-quenching method. The absorption spectra and upconversion spectra of the glass were measured, and the upconversion luminescence mechanism was analyzed. Intensive red (662 nm), green (546 nm) and blue (480 nm) emissions of the tellurite glass were simultaneously observed at room temperature under 975 nm LD excitation. Upconversion red luminescence are due to the energy transition of Tm3+ ion: 1G4→3F4 and Ho3+ ion: 5F5→5I8, while upconversion green and blue are the results of Ho3+ ion: 5S2→5I8 and Tm3+ ion: 5S2(5F4) →5I8, respectively. With the increasing of Yb3+ content and the pump power, upconversion luminescence are also enhanced. The white light close to the standard white light emission has been obtained by adjusting the concentration of rare earth doping. Our result has practical significance for developing high-quality white LED. |
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| Keywords: | tellurite glasses upconversion luminescence white light Tm3+/Ho3+/Yb3+ codoping |
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