Knight shifts of27Al and magnetic susceptibility of intermetallic compound NiAl with Fe additions |
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Authors: | D Goldberg A Shevakin M Fradkin A Belenkii E Kulefeeva |
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Institution: | (1) Central Scientific Research Institute for Ferrous Metallurgy, 107843 Moskow, USSR |
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Abstract: | Atomic and electronic structures, magnetic properties of intermetallic compound NiAl with Fe additions (up to IO at .% for
different types of alloying) were studied using NMR and magnetic susceptibility measurements. The effect of these parameters
on the probability of occurence of phase transformation B2-LIo was explored. Experimental results were compared with those obtained by computer calculations of the electronic structure
for atomic arrangement of Fe impurity in both sublattices by means of the cluster variant of TBA-LCAO method. The responsibility
of the density of 3d-states at the Fermi level increasing effects (Fe−Ni substitution) and corresponding contributions, associated
with orbital interactions (Fe−Al substitution), for observed behaviour of measured parameters were determined. Appearance
of B2-LIo phase transition with increasing of antistructural Fe atoms (ASA) concentration was observed experimentally by means of transmission
electron microscopy and X-ray diffraction analysis. |
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