Vibrational relaxation by collision in polyatomic molecules |
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Authors: | E E Nikitin |
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Institution: | (1) Institute of Chemical Physics, AS USSR, Moscow |
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Abstract: | A model of a harmonic oscillator with friction is used to discuss the conversion of translational energy to vibrational by collision of an atom with a polyatomic molecule. It is shown that adiabatic conversion implies that ![lang](/content/p4886jlk5q41k728/xxlarge9001.gif) E
2 may substantially exceed the value calculated, neglecting the interaction of the bond with the rest of the molecule. |
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Keywords: | |
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