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Concise synthesis of (-)-anisomycin |
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| Authors: | Ji Lia Yan Hua Fenga Xin Bai Lia Wei Hana Huan Qiu Liua Guo Guang Shaob a |
| Institution: | Department of Anesthesiology, The First Hospital of Jilin University, Changchun 130021, China ; Department of Thoracic Surgery, The First Hospital of Jilin University, Changchun 130021, China |
| Abstract: | The antibiotic(-)-anisomycin was synthesized starting from D-tyrosine using Sharpless asymmetric epoxidation as a key reaction followed by formation and hydrolysis of oxazoline set up all chiral center. |
| Keywords: | Anisomycin D-Tyrosine Sharpless asymmetric epoxidation Oxazoline |
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