Photochemical water reduction by molybdenum tetrachloride |
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| Authors: | Kunkely Horst Vogler Arnd |
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| Institution: | (1) Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg, Germany |
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| Abstract: | The photolysis of MoCl4(MeCN)2 in MeCN in the presence of small amounts of H2O proceeds according to the equation MoIVCl4·H2O MoVIOCl4 + H2. It is suggested that a ligand field excited state of MoCl4(H2O)
n
, which is initially populated by light absorption, is deactivated to a reactive metal-to-ligand (MoIVH2O) charge transfer state. |
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