Synthesis of silyl aziridines and alpha-amino acylsilanes with silyldibromomethyllithium |
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| Authors: | Yagi Kazunari Shinokubo Hiroshi Oshima Koichiro |
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| Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan. |
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| Abstract: | The reaction of silyldibromomethyllithium with aromatic imines provides alpha-amino acylsilanes via a bromo aziridine intermediate upon quenching the reaction with water. Alternatively, treatment of the bromo aziridine intermediate with various Grignard reagents or lithium aluminum hydride permits the nucleophilic displacement of the halogen to furnish substituted silyl aziridines. |
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