Radical reactions in malonic acid single crystal between 4 K and 300 K |
| |
| Authors: | M Kikuchi N Leray J Roncin B Joukoff |
| |
| Institution: | Laboratoire de Résonance Electronique et Ionique, Université de Paris-Sud, Centre d''Orsay - 91405 Orsay, France;CNET Department PEC/CCM, 196 rue de Paris - 92 Bagneux, France |
| |
| Abstract: | For three out of the four different radicals which are produced by γ-irradiation in malonic acid single crystals, two stereo-isomers have been observed. The structures and orientations of these radicals were determined. ?H2COOH proceeds from the cation and is already formed at 4 K; as to H?(COOH)2, it proceeds from the molecular form of the protonated anion COOHCH2?(OH)2. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
