| 含苯并咪唑锌配合物的合成、表征及晶体结构 |
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| 引用本文： | 朱 莉,廖展如,龙云飞,刘胜利,田 莉,张 磬. 含苯并咪唑锌配合物的合成、表征及晶体结构[J]. 无机化学学报, 2004, 20(4): 399-402 |
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| 作者姓名： | 朱 莉 廖展如 龙云飞 刘胜利 田 莉 张 磬 |
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| 作者单位： | 1. 湖南科技大学化学化工学院,湘潭,411100
2. 华中师范大学化学学院,武汉,430070 |
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| 基金项目： | 湖南省自然科学基金资助项目(No.O2JJY2018)，院重点学科鄄无机化学资助课题。 |
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| 摘 要： | The complex of [N,N,N′,N′-tetrakis(2-benzimida zolyl methyl)-1,4-diethylene amino]-glycol ether (EGTB) with zinc(Ⅱ), [Zn2(EGTB)Cl2](ClO4)2·CH3OH·3H2O was synthesized and characterized with element analysis , UV and IR spectroscopy, and X-ray diffraction method. The crystal belongs to monoclinic with space group of P21/c. The cell parameters are a=1.437 6(2) nm, b=2.526 50(4) nm, c=1.435 31(2) nm, β=101.7037(8) °, Z=4, F(000)=2 376, Dc=1.503g·cm-3, The final R=0.080 4, wR2=0.2236. Biological activities of the complexe was traced by UV-Vis spectrum. The result demonstrates that the complexe has good catalytic abliliy. CCDC: 180994.
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| 关 键 词： | 合成 晶体结构 含苯并咪唑锌配合物 生物活性 |
| 修稿时间： | 2003-05-05 |
Syntheses and Crystal Stuctures of Znic(Ⅱ) Complex Containing Benzimidazolyl |
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| ZHU Li,LIAO Zhan-Ru,LONG Yu-Fei,LIU Sheng-Li,TIAN Li and ZHANG Xin. Syntheses and Crystal Stuctures of Znic(Ⅱ) Complex Containing Benzimidazolyl[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(4): 399-402 |
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| Authors: | ZHU Li LIAO Zhan-Ru LONG Yu-Fei LIU Sheng-Li TIAN Li ZHANG Xin |
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| Affiliation: | College of Chemistry and Chemical Engineering, Hunan Technology University, Xiantan 411100,Department of Chemistry, Huazhong Normal University, Wuhan 430070,College of Chemistry and Chemical Engineering, Hunan Technology University, Xiantan 411100,College of Chemistry and Chemical Engineering, Hunan Technology University, Xiantan 411100,College of Chemistry and Chemical Engineering, Hunan Technology University, Xiantan 411100 and College of Chemistry and Chemical Engineering, Hunan Technology University, Xiantan 411100 |
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| Abstract: | |
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| Keywords: | synthesis crystal structure zinc complexe with benzi midazolyl biological activity |
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