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meso-四(3,5-二溴-4-羟基苯)卟啉及其与铅的灵敏显色反应的研究
引用本文:徐钟隽,吴怀琴,潘教麦.meso-四(3,5-二溴-4-羟基苯)卟啉及其与铅的灵敏显色反应的研究[J].化学学报,1989,47(9):918-921.
作者姓名:徐钟隽  吴怀琴  潘教麦
作者单位:华东师范大学化学系
摘    要:本文报导了新合成的卟啉试剂meso-四(3,5-二溴-4-羟基苯)卟啉T(DBHP)P], 研究了它的性质及其与Pb^2^+的反应条件, 制定了测定痕量Pb^2^+的新光度法, 该法灵敏度甚高(δ=2.40×10^5), 在8-羟基喹啉存在下, 反应可在室温下迅速进行, 甚选择性也甚好, 可成为光度测量痕量Pb^2^+的优良方法。

关 键 词:苯酚P  卟吩P  灵敏度    显色反应  羟基喹啉类  有机试剂  

meso-tetra-(3,5-dibromo-4-hydroxyphenyl) porphyrin and its sensitive color-reaction with lead
XU ZHONGJUAN,WU HUAIQIN,PAN JIAOMAI.meso-tetra-(3,5-dibromo-4-hydroxyphenyl) porphyrin and its sensitive color-reaction with lead[J].Acta Chimica Sinica,1989,47(9):918-921.
Authors:XU ZHONGJUAN  WU HUAIQIN  PAN JIAOMAI
Abstract:The synthesis of meso-tetrakis(3,5-dibromo-4-hydroxyphenyl)porphyrinT(DBHP)P] is described. The conditions of the reaction of lead with T(DBHP)P] were studied and a highly sensitive method for spectrophotometric determination of microamounts of lead was developed. The complex-formation reaction in alkaline solution can be accelerated at room temperature in the presence of oxine. The Soret band lies at 479 nm with an apparent molar absorptivity of 2.40 ?105 dm3 mol-1. The composition of the complex is 1:2 Pb:T(DBHP)P. Beer's law is obeyed up to 11 mg Pb/25 mL. The interferences of foreign ions were examined and the selectivity is fairly good as compared with the reactions by using other porphyrins.
Keywords:PHENOL P  PORPHINE P  SENSITIVITY  LEAD  COLOR REACTION  HYDROXY QUINOLINES  ORGANIC REAGENTS
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