| 示差脉冲极谱法研究 IX: 准可逆波和不可逆波理论及其验证 |
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| 引用本文： | 张剑荣,张祖训. 示差脉冲极谱法研究 IX: 准可逆波和不可逆波理论及其验证[J]. 化学学报, 1989, 47(8): 751-755 |
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| 作者姓名： | 张剑荣 张祖训 |
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| 作者单位： | 南京大学化学系 |
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| 摘 要： | 本文提出了受扩散和电极反应速率控制的示差脉冲极谱波方程式, 它推导过程简单, 具有明确的形式和涵义, 以镍(II)和锌(II)-硝磷钾体系进行验证, 实验结果与理论相符。
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| 关 键 词： | 示波极谱法 电极 脉冲极谱法 极谱分析 反应速度 波导理论 |
Investigation on differential pulse polarography IX: Theory and its experimental verification for quasireversible and totally irreversible wave |
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| ZHANG JIANRONG,ZHANG ZUXUN. Investigation on differential pulse polarography IX: Theory and its experimental verification for quasireversible and totally irreversible wave[J]. Acta Chimica Sinica, 1989, 47(8): 751-755 |
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| Authors: | ZHANG JIANRONG ZHANG ZUXUN |
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| Abstract: | An equation was derived theor. for quasireversible and totally irreversible differential pulse polarog. wave which was in good agreement with experimental reduction of Ni2+ and Zn2+ in 0.1 and 1.0 mol/dm3 KNO3, resp. |
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| Keywords: | OSCILLOSCOPIC POLAROGRAPHY ELECTRODE PULSE POLAROGRAPHY POLAROGRAPHIC ANALYSIS REACTION RATE WAVEGUIDE THEORY |
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