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Why [CpW(CO)3]+ reduces H2 to dihydride |
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| Authors: | Lesnard Hervé Demachy Isabelle Jean Yves Lledos Agusti |
| Affiliation: | Laboratoire de Chimie Physique, UMR 8000, Université Paris Sud 11, Centre d'Orsay, 91 405 Orsay Cedex, France. |
| Abstract: | The [CpW(CO)3]+ complex, with three pi acceptor ligands and a positive charge, is shown to have an unexpected reducing ability towards H2 because of a low lying triplet state energy. |
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