Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes |
| |
| Authors: | García-López Jesús Peralta-Pérez Emma Forcén-Acebal Angela García-Granda Santiago López-Ortiz Fernando |
| |
| Affiliation: | Area de Química Orgánica, Universidad de Almería, Carretera de Sacramento s/n, 04120, Almería, Spain. |
| |
| Abstract: | The first examples of the PN-directed dilithiation of (N-methoxycarbonyl)phosphazenes in the C(alpha) and C(ortho) to the phosphorus, and the use of these dianions in the formation of tri- and tetra-substituted olefins through stereospecific thermolysis of a new type of isolable bicyclic 1,2-oxaphosphetanes are described. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
