An unprecedented alpha-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex |
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| Authors: | Jaffart Joëlle Etienne Michel Reinhold Meike McGrady John E Maseras Feliu |
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| Affiliation: | Laboratoire de Chimie de Coordination du CNRS, UPR8241, 205 Route de Narbonne 31077, Toulouse, France. |
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| Abstract: | Structural, spectroscopic and theoretical evidence indicate that an unusual alpha-C-C agostic interaction is preferred over both alpha- and beta-C-H agostic alternatives in the title compound, TpMe2NbCl(c-C3H5)(MeCCMe). |
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