Conversions of Allyl Ethers in a Superbasic Medium |
| |
| Authors: | Vyglazov O G Chuiko V A Izotova L V |
| |
| Institution: | (1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus;(2) Tereza-Inter Company, Moscow, Russia |
| |
| Abstract: | Conversions of alkyl allyl and terpenoid allyl ethers in a superbasic medium (dimethyl sulfoxidepotassium hydroxide) are studied. The ethers with an unbranched alkyl substituent isomerize into propenyl ethers, the ethers with a branched unsaturated substituent decompose to give a hydrocarbon, and diallyl ethers isomerize into allyl vinyl ethers whose Claisen rearrangement gives rise to aldehydes. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
