Porous lanthanide-organic framework with zeolite-like topology |
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| Authors: | Maji Tapas Kumar Mostafa Golam Chang Ho-Chol Kitagawa Susumu |
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| Affiliation: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | Two novel isomorphous porous frameworks of Ln(III), {[Ln2(imidc)2(H2O)3](H2O)}n, [Ln = Gd(III) (1) and Er(III) (2)] have been synthesized hydrothermally using multifunctional 4,5-imidazoledicarboxylic acid (imidc) as a connector; they have a zeolite-like network topology which can provide another form upon dehydration, and exhibit selective adsorption properties for H2O over N2, CO2 and MeOH. |
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