Surfactant properties of ionic liquids containing short alkyl chain imidazolium cations and ibuprofenate anions |
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Authors: | Tourné-Péteilh Corine Devoisselle Jean-Marie Vioux André Judeinstein Patrick In Martin Viau Lydie |
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Institution: | Institut Charles Gerhardt Montpellier, UMR 5253, CNRS-UM2-ENSCM-UM1 Place Eugène Bataillon, CC007, 34095 Montpellier Cédex, France. |
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Abstract: | Interfacial tension, electrical conductivity, NMR self-diffusion and DLS experiments have been used to investigate the self-aggregation in water of ionic liquids associating an ibuprofenate anion and 1-alkyl-3-methylimidazolium C(n)MIm](+) (n = 4, 6, 8) cations. Despite the short alkyl chain on imidazolium cations (n ≤ 8), these ionic liquids exhibit particularly low Critical Aggregation Concentrations (CAC), significantly lower than their parent 1-alkyl-3-methylimidazolium chloride salts. This behaviour is attributed to the formation of catanionic pairs between ibuprofenate and imidazolium. |
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