Polyfluorination of aryl alkyl sulfides by IF5 with concomitant migration of the arylthio group |
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| Authors: | Ayuba Shinichi Fukuhara Tsuyoshi Hara Shoji |
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| Institution: | Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan. |
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| Abstract: | reaction: see text] In the reaction of p-chlorophenyl alkyl sulfides with IF(5), polyfluorination reaction took place on the alkyl chain with the migration of the arylthio group. Consequently, p-chlorophenyl polyfluoroalkyl sulfides, having 3-7 fluorine atoms depending on alkyl chain length, could be obtained selectively. |
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