| 氧化法合成烃基磺酰氯 |
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| 引用本文： | 康汝洪,武瑞涛,甄小丽.氧化法合成烃基磺酰氯[J].有机化学,1998,18(6):559-561. |
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| 作者姓名： | 康汝洪 武瑞涛 甄小丽 |
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| 作者单位： | 河北师范大学化学系，河北师范大学化学系，河北科技大学基础部 石家庄 050016，石家庄 050016，石家庄 050018 |
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| 摘 要： | 以S-烃基异硫脲盐、硫氰酸酯、硫醚为底物,在盐酸介质中,温和条件下,通过氧化法高产率地合成了烃基磺酰氯;探讨了氧化剂作用机理;合成中采用PTC技术,使产品收率可提高30%。
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| 关 键 词： | 相转移催化 烷基磺酸盐 酰氯P 合成 氧化法 硫脲类 硫氰酸酯 硫醚 作用机理 氧化剂 |
A preparation of hydrocarbyl sulfuryl chloride by the oxidation of sulfocompounds |
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| KANG Ru - Hong WU Rui - Tao.A preparation of hydrocarbyl sulfuryl chloride by the oxidation of sulfocompounds[J].Chinese Journal of Organic Chemistry,1998,18(6):559-561. |
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| Authors: | KANG Ru - Hong WU Rui - Tao |
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| Institution: | Hebei Teachers Univ, Dept Chem.Shijiazhuang(050016) |
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| Abstract: | Hydrocarbyl sulfuryl chloride was prepared by the oxidation of S - hydrocarbyl isothiouronium salts, thiocyanic esters and sulfuric ether in the medium of hydrochloric acid under mild conditions with high yields. The use of phase transfer catalysis could make the yield increased by 30% . In addition, the mechanism of oxidation process was briefly discussed. |
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| Keywords: | sulfuryl chloride oxidant S - hydrocarbyl isothiouronium salt phase transfer catalysis |
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