Indirect electrochemical destructive oxidation of aromatic compounds with reactive oxygen species |
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| Authors: | V L Kornienko N V Chaenko G V Kornienko |
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| Institution: | (1) Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, ul. K. Marksa 42, Krasnoyarsk, 660049, Russia |
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| Abstract: | The indirect destructive electrooxidation of benzene, phenol, and N-methyl-p-aminophenol with active oxygen species generated in situ from O2, H2O2, and H2O in aqueous solutions with various pH values has been carried out using different cell designs with Pt, Pb/PbO2, and Ru-Ti oxide anodes. The indirect oxidation of the aromatic compounds mineralizes them into CO2 and H2O or converts them into simple monocarboxylic or dicarboxylic acids, which can be utilized by microorganisms in subsequent biotreatment. |
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| Keywords: | indirect oxidation hydrogen peroxide oxygen gas-diffusion cathode benzene phenol N-methyl-p-aminophenol |
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