| 摘 要： | The crystal structure of meso-tetrakis(4-hydroxyphenyl)porphyrinato manganese chloride(MnTHPPCl)and its supramolecular architecture based on the hydrogen bonds of one counter Cl anion with four hydrogen atoms of four-OH groups from different MnTHPPCl molecules cooperated by self-assembly of the porphyrin units were first reported.This compound crystallized in the tetragonal space group I4/m with a=1.39928(7)nm,b=1.39928(7)nm,c=0.94498(10)nm,V=1.8503(2)nm3,and Z=2.As a catalyst,MnTHPPCl also showed a high catalytic acti-vity in the conversion from 1-naphthylamine(1-NA)to bis(4-oxo-benzo-2-cyclohexen-1-yl)amine(BOBCHA)via oxidative coupling under mild conditions.
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