| Crystal Structure and Catalytic Properties of Tetrakis (4-hydroxyphenyl) Porphyrinato Manganese(Ⅲ) Chloride (MnTHPPCl) |
| |
| 作者单位： | YANG Jun-wei，HUANG Xiao-chun，LIU Jin-bin，CHEN Tie，XIANG Jing，TONG Shan-ling，YANG Ke-er and YAN Yan Department of Chemistry，Shantou University，Shantou 515063，P.R.China |
| |
| 摘 要： | The crystal structure of meso-tetrakis(4-hydroxyphenyl)porphyrinato manganese chloride(MnTHPPCl)and its supramolecular architecture based on the hydrogen bonds of one counter Cl anion with four hydrogen atoms of four-OH groups from different MnTHPPCl molecules cooperated by self-assembly of the porphyrin units were first reported.This compound crystallized in the tetragonal space group I4/m with a=1.39928(7)nm,b=1.39928(7)nm,c=0.94498(10)nm,V=1.8503(2)nm3,and Z=2.As a catalyst,MnTHPPCl also showed a high catalytic acti-vity in the conversion from 1-naphthylamine(1-NA)to bis(4-oxo-benzo-2-cyclohexen-1-yl)amine(BOBCHA)via oxidative coupling under mild conditions.
|
Crystal Structure and Catalytic Properties of Tetrakis(4-hydroxyphenyl) Porphyrinato Manganese (Ⅲ) Chloride (MnTHPPCl) |
| |
| Authors: | YANG Jun-wei HUANG Xiao-chun LIU Jin-bin CHEN Tie XIANG Jing TONG Shan-ling YANG Ke-er YAN Yan |
| |
| Abstract: | The crystal structure of meso-tetrakis(4-hydroxyphenyl)porphyrinato manganese chloride(MnTHPPCl)and its supramolecular architecture based on the hydrogen bonds of one counter Cl anion with four hydrogen atoms of four-OH groups from different MnTHPPCl molecules cooperated by self-assembly of the porphyrin units were first reported.This compound crystallized in the tetragonal space group I4/m with a=1.39928(7)nm,b=1.39928(7)nm,c=0.94498(10)nm,V=1.8503(2)nm3,and Z=2.As a catalyst,MnTHPPCl also showed a high catalytic acti-vity in the conversion from 1-naphthylamine(1-NA)to bis(4-oxo-benzo-2-cyclohexen-1-yl)amine(BOBCHA)via oxidative coupling under mild conditions. |
| |
| Keywords: | Crystal structure Metalloporphyrin Catalytic property |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
