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Synthesis and mesomorphic properties of fluoro and isothiocyanato biphenyl tolane liquid crystals
Authors:Yung-Ming Liao   Narayanasamy Janarthanan  Chain-Shu Hsu  Sebastian Gauza  Shin-Tson Wu
Affiliation: a Department of Applied Chemistry, National Chiao Tung University, Hsinchu 30010, Taiwan, R.O.Cb College of Optics and Photonics, University of Central Florida, Orlando, FL 32816
Abstract:Four series of high birefringence biphenyl tolane liquid crystals having a terminal isothiocyanato or fluoro group were synthesized; their mesomorphic properties were studied by optical polarizing microscopy and DSC. These biphenyl tolane compounds exhibit reasonably low melting points and high birefringence of 0.37-0.49. By using these compounds a eutectic mixture was formulated exhibiting a wide nematic range, high figure-of-merit and low viscosity.
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