Ultrastable Imine‐Based Covalent Organic Frameworks for Sulfuric Acid Recovery: An Effect of Interlayer Hydrogen Bonding |
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| Authors: | Arjun Halder Suvendu Karak Dr Matthew Addicoat Saibal Bera Dr Amit Chakraborty Shebeeb H Kunjattu Dr Pradip Pachfule Prof Dr Thomas Heine Prof Dr Rahul Banerjee |
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| Institution: | 1. Academy of Scientific and Innovative Research (AcSIR), Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune-, India;2. School of Science and Technology, Nottingham Trent University, Nottingham, UK;3. Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune-, India;4. Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Pune, India;5. Wilhelm-Ostwald-Institute for Physical and Theoretical Chemistry, University of Leipzig, Leipzig, Germany;6. Physical/Materials Chemistry Division, CSIR-National Chemical La-boratory, Pune-, India;7. Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur, India |
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| Abstract: | A rapid and scalable synthesis of six new imine‐linked highly porous and crystalline COFs is presented that feature exceptionally high chemical stability in harsh environments including conc. H2SO4 (18 m ), conc. HCl (12 m ), and NaOH (9 m ). This is because of the presence of strong interlayer C?H???N hydrogen bonding among the individual layers, which provides significant steric hindrance and a hydrophobic environment around the imine (?C=N?) bonds, thus preventing their hydrolysis in such an abrasive environment. These COFs were further converted into porous, crystalline, self‐standing, and crack‐free COF membranes (COFMs) with extremely high chemical stability for their potential applications for sulfuric acid recovery. The as‐synthesized COFMs exhibit unprecedented permeance for acetonitrile (280 Lm?2 h?1 bar?1) and acetone (260 Lm?2 h?1 bar?1). |
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| Keywords: | covalent organic frameworks hydrogen bonding imines membranes ultrahigh stability |
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