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Binding Matter with Antimatter: The Covalent Positron Bond
Authors:Jorge Charry  Prof. Márcio T. do N. Varella  Prof. Andrés Reyes
Affiliation:1. Universidad Nacional de Colombia Chemistry, Bogota, 00000, Colombia;2. Instituto de Física, Universidade de S?o Paulo, S?o Paulo, SP, Brazil
Abstract:We report sufficient theoretical evidence of the energy stability of the e+?H22? molecule, formed by two H? anions and one positron. Analysis of the electronic and positronic densities of the latter compound undoubtedly points out the formation of a positronic covalent bond between the otherwise repelling hydride anions. The lower limit for the bonding energy of the e+?H22? molecule is 74 kJ mol?1 (0.77 eV), accounting for the zero‐point vibrational correction. The formation of a non electronic covalent bond is fundamentally distinct from positron attachment to stable molecules, as the latter process is characterized by a positron affinity, analogous to the electron affinity.
Keywords:Ab initio calculations  bond energy  covalent bonds  positron chemistry  quantum chemistry
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