Intermolecular Arrangement of Fullerene Acceptors Proximal to Semiconducting Polymers in Mixed Bulk Heterojunctions |
| |
| Authors: | Dr Chao Wang Dr Kyohei Nakano Dr Hsiao Fang Lee Yujiao Chen Dr You‐Lee Hong Dr Yusuke Nishiyama Dr Keisuke Tajima |
| |
| Institution: | 1. RIKEN Center for Emergent Matter Science (CEMS), Wako, Saitama, Japan;2. RIKEN CLST-JEOL Collaboration Center, Yokohama, Kanagawa, Japan;3. JEOL RESONANCE Inc., Musashino, Akishima, Tokyo, Japan |
| |
| Abstract: | Precise control of the molecular arrangements at the interface between the electron donor and acceptor in mixed bulk heterojunctions (BHJs) remains challenging, despite the correlation between structural characteristics and efficiency in organic photovoltaics (OPVs). This study reveals that the substitution patterns of linear and branched alkyl side chains on electron‐donating/‐accepting alternating copolymers can control the positions of an acceptor molecule (C60) around the π‐conjugated main chains in mixed BHJs. Two‐dimensional solid‐state NMR demonstrates a marked difference in the location of C60 in the blend films. A copolymer with an electron‐accepting unit positioned in close proximity to C60 demonstrated higher OPV performance in combination with various fullerene derivatives. This molecular design offers precise control over the interfacial molecular structure, thereby paving the way for overcoming the current limitations of OPVs comprising mixed BHJs. |
| |
| Keywords: | C60 intermolecular arrangement nanotechnology NMR spectroscopy semiconducting polymers |
|
|
