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Metal‐Catalyzed Remote Functionalization of ω‐Ene Unsaturated Ethers: Towards Functionalized Vinyl Species
Authors:Dr Guo‐Ming Ho  Lina Judkele  Dr Jeffrey Bruffaerts  Prof Dr Ilan Marek
Institution:Schulich Faculty of Chemistry, Technion—, Israel Institute of Technology, Haifa, Israel
Abstract:The combined ruthenium‐catalyzed chain walking with the nickel‐catalyzed cross‐coupling reaction of ω‐alkenyl ethers provide a unique entry to functionalized vinyl species. This transformation illustrates the power and flexibility of remote functionalization by demonstrating the compatibility of two independent reactions involving unrelated sites.
Keywords:cross-coupling  isomerization  nickel  remote functionalization  zirconium
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