Diels–Alder reactivity of 2-(bromomethyl)-1,4-quinone and 2-bromo-5-(bromomethyl)-1,4-quinone with cyclopentadiene and the synthesis of new substituted pentacyclic systems |
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| Authors: | Uma Sudhir Beena James S Joly Mangalam S Nair |
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| Institution: | (1) Department of Chemistry and Center for Plastic Information System, Pusan National University, San 30 Jangjeon-Dong, Geumjeong-Gu, Busan, 609-735, Korea; |
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| Abstract: | Photochemical synthesis of the novel compounds 3-bromotetracyclo 5.3.1.02,6.04,8] undec-10(12)-ene-9,11-dione, 1-(bromomethyl)pentacyclo 5.4.0.02,6.03,10.05,9]undeca-8,11-dione and 1-bromo-9-(bromomethyl)pentacyclo 5.4.0.02,6.03,10.05,9]undeca-8,11-dione is described. |
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| Keywords: | DIELS-ALDER REACTIVITY BROMOMETHYLQUINONES POLYCYCLIC CAGE COMPOUNDS 13C-NMR |
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