Synthesis of some cis-dioxomolybdenum complexes and their use in the epoxidation of olefins |
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| Authors: | D D Agarwal Savita Shrivastava |
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| Institution: | School of Studies in Chemistry, Jiwaji University, Gwalior—474011, M.P., India |
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| Abstract: | The cis-dioxomolybdenum complexes MoO2(L) (L = HPD, APAC, AAC, ACEN and APS) have been synthesized and characterized. The epoxidation of olefins has been studied using these molybdenum complexes as catalysts and tert-butylhydroperoxide (TBHP) as oxidant. The studies suggest that these complexes, except MoO2(APAC)], did not demetallate during the reaction. |
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