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Synthesis of acrylic acid-based superabsorbent interpenetrated with sodium PVA sulfate using inverse-emulsion polymerization
Authors:Doo-Won LimKyong-Geun Song  Kee-Jong YoonSohk-Won Ko
Affiliation:a Department of Fiber and Polymer Science, Seoul National University, Seoul 151-742, South Korea
b Department of Textile Engineering, Chonbuk National University, Chonju, Chonbuk 561-756, South Korea
c Department of Textile Engineering, Dankook University, Seoul 140-714, South Korea
Abstract:Acrylic acid (AA)-based superabsorbent interpenetrated with sodium poly(vinyl alcohol) (PVA) sulfate (SPS) was prepared by inverse-emulsion polymerization. The disperse phase was prepared by dissolving AA and crosslinking monomer in aqueous SPS solution. Toluene was used as the continuous phase in which oil-soluble initiator and emulsifiers were dissolved. Sorbitan monooleate and ethyl cellulose were used as emulsifiers. The maximum water and saline absorbencies were 5041 and 211.4 g/g, respectively.
Keywords:Acrylic acid   Sodium PVA sulfate   Interpenetrating   Inverse-emulsion polymerization   Superabsorbent
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