Preparation of polymeric sheet porphyrin complexes and their environmentally benignly catalytic activity |
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| Authors: | Yu-Feng HeRong-Min Wang Yun-Pu WangChun-Gu Xia |
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| Affiliation: | a Institute of Polymer, Northwest Normal University, Lanzhou 730070, China
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
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| Abstract: | The polymeric meso-tetra-(1,5-naphthalene bisulfonyloxo)phenylporphyrin and its complexes (PTNBSOPPM, M=Co, Mn, Fe) have been prepared in the presence of phase-transfer catalyst. Catalyzed by polymeric porphyrin complexes (PTNBSOPPM), styrene can be aerobic oxidized. The main products come from cleavage of double bond is in catalytic oxidation of styrene or α-methyl styrene. |
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| Keywords: | Polymeric sheet porphyrin Dioxygen Environmental benign |
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