|
|||||
|
|
Reductive dimerization of dialkyl acetylenedicarboxylate catalyzed by [Rh(binap)(MeOH)2]ClO4 in methanol |
|
| Authors: | Kazuhide Tani Kazuya Ueda Kenji Arimitsu Tsuneaki Yamagata Yasutaka Kataoka |
| Abstract: | Cationic Rh(I) complex Rh(binap)(MeOH)2]ClO4 catalyzes reductive dimerization of dialkyl acetylenedicarboxylates 1 to give 1,2,3,4-tetrakis(alkoxycarbonyl)-1,3-butadienes 2 in methanol selectively. |
| Keywords: | Dimerization Cationic Rhodium |
| 本文献已被 ScienceDirect 等数据库收录！ | |