Synthesis, structure and luminescent property of a 2D polymer containing silver ions |
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| Authors: | Bin Zhao Xiao-Qing Zhao Wei Shi Peng Cheng |
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| Institution: | aDepartment of Chemistry, Nankai University, Tianjin 300071, PR China |
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| Abstract: | Silver(I) complex with 4,5-dicarboxyimidazole (H3dcbi) has been synthesized by hydrothermal method and proven to be a novel 2D coordination polymer Ag(H2dcbi)]n (1), which crystallized in monoclinic crystal system and space group of P2(1)/c. Each Ag(I) ion is coordinated to three O atoms and one N atom, which completes the trigonal pyramidal geometry of Ag(I) ion. Solid-state fluorescent emission spectra of 1 were investigated. |
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| Keywords: | Silver(I) complex Crystal structure Coordination polymer Fluorescence |
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