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Poly(dimethylaminoethylmethacrylate) hydrochloride (PDMAEM-HCl) a well behaving polycation for multilayer formation on planar surfaces
Authors:Angel Licea-Claverıe  Simona Schwarz  Frank Simon  Omar Urzúa-Sánchez  Jürgen Nagel  Dieter Pleul  Klaus-Jochen Eichhorn  Andreas Janke
Institution:(1) Instituto Tecnológico de Tijuana, Centro de Graduados e Investigación, A.P. 1166, 22000 Tijuana, BC, México;(2) Institute of Polymer Research Dresden, Hohe Str. 6, 01069 Dresden, Germany
Abstract:The polycation preparation of poly(dimethylaminoethylmethacrylate) hydrochloride and the multilayer formation in combination with poly(sodium 4-styrenesulphonate) as polyanion studies onto different substrates, as followed by streaming potential measurements, in situ surface plasmon resonance spectroscopy, and multi-wavelength ellipsometry, are reported. Furthermore, we studied the resulting multilayer buildup of dry surfaces by UV-Vis spectroscopy, X-ray photoelectron spectroscopy, and atomic force microscopy measurements. Thereby, the layer built up at the solid/liquid-interface could be followed and quantified at the molecular level.This revised version was published online in April 2005 with corrections to the article category.
Keywords:Polyelectrolyte adsorption  Multilayers  Self-assembly  Surface modification  Surface functionalization
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