Trimethylaminedichlorogailane (Cl2Ga · NMe3)2 with the Ga-Ga intermetallic bond |
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| Authors: | A. Yu. Pashkov V. K. Belsky M. Butychev T. M. Zvukova |
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| Affiliation: | (1) Department of Chemistry, M. V. Lomonosov Moscow State University, Vorobévy Gory, 119899 Moscow, Russian Federation |
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| Abstract: | The reaction of GaH3 · NMe3 with ClPBut2 in ether occurs through the exchange of ligands followed by reduction of Ga3+ to Gaz+ to yield (GaCl2 · NMe3)2. X-ray structural analysis demonstrated that gallium atoms in this compound form a direct metal-metal bond with the length of 2.421 Å.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2078–2081, August, 1996. |
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| Keywords: | gallium gallanes metal-metal bond structure |
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