Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine) |
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| Authors: | Cinellu Maria A Minghetti Giovanni Stoccoro Sergio Zucca Antonio Manassero Mario |
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| Institution: | Dipartimento di Chimica, Universita di Sassari, via Vienna 2, I-07100 Sassari, Italy. cinellu@uniss.it |
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| Abstract: | Gold alkene complexes Au(bipyR)(eta2-alkene)]PF6] (bipyR = 6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes Au2(bipyR)2(mu-O)2]PF6]2 with alkenes. The crystal structure of the styrene adduct Au(bipy(ip))(eta2-CH2=CHPh)]PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine) has been solved by X-ray analysis. |
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