Naked-eye detection of cyanide ions in aqueous media based on an azo-azomethine chemosensor |
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Institution: | Department of Chemistry, Faculty of Sciences, Arak University, Dr. Beheshti Ave., Arak 38156-8-8349, Iran |
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Abstract: | The optical and colorimetric properties of a new chemosensor 4-((2,4-dichlorophenyl)diazenyl)-2-(3-hydroxypropylimino)methyl)phenol (L) for cyanide ions were investigated by the naked-eye detection and UV–vis spectroscopy. This receptor reveals visual changes toward CN? anions in aqueous media. No significant color changes were observed upon the addition of any other anions. The cyanide recognition properties of the receptor through proton-transfer were monitored by UV–vis titration and 1H NMR spectroscopy. The binding constant (Ka) and stoichiometry of the formed host–guest complex were calculated by the Benesi–Hildebrand (B–H) plot and Job's plot method, respectively. The detection limit of the probe towards CN? was 1.03 × 10?6 mol L?1, which is lower than the maximum value of cyanide (1.9 × 10?6 mol L?1) permitted by the World Health Organization in drinking water. Thus, this chemosensor was sensitive enough to detect cyanide in aqueous solutions. 1H NMR experiments were conducted to investigate the nature of interaction between the receptor and CN? anions. Notably, the designed sensor can be applied for the rapid detection of cyanide anions in the basic pH range and also under physiological conditions, for practical purposes for a long duration. The sensing behavior of the receptor was further emphasized by computational studies. Quantum-chemical calculations and molecular studies via Density Functional Theory (DFT) were carried out to supplement the experimental results. |
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Keywords: | Cyanide ions Naked-eye detection Chemosensor Azo-azomethine |
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