A new enantiopure unsaturated dicarboxylate as a 4-connected unit in a flexible homochiral PtS-type framework |
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| Authors: | Zhang Jian Bu Xianhui |
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| Institution: | Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA. |
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| Abstract: | Metal cation mediated chiral ligand transformation of (S)-camphanic acid leads to a new enantiopure unsaturated dicarboxylate that links tetrahedral Zn(2+) sites into 3-D homochiral 4-connected PtS-type framework structures, Zn(tced) (1, H(2)tced=1,2,2-trimethyl-3-cyclopentene-1,3-dicarboxylic acid) and Zn(4)(tced)(4)(4,4'-bipy) (2, 4,4'-bipy=4,4'-bipyridine). |
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