| Crystal Structure of a Novel Cadmium Coordination Polymer [Cd15（OH）4（SO4）4（L1）6（L2）12]n （HL1 = 1,2,3-1H-Triazole,HLe = 5-Methyl-lH-tetrazole |
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| 引用本文： | ZHANG Quan-Zheng,;XIA Chang-Kun,;TIAN Chang-An,;LU Hong-Dian. Crystal Structure of a Novel Cadmium Coordination Polymer [Cd15（OH）4（SO4）4（L1）6（L2）12]n （HL1 = 1,2,3-1H-Triazole,HLe = 5-Methyl-lH-tetrazole[J]. 结构化学, 2009, 28(9): 1167-1171 |
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| 作者姓名： | ZHANG Quan-Zheng, XIA Chang-Kun, TIAN Chang-An, LU Hong-Dian |
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| 作者单位： | [1]Department of Chemistry ＆ Materials Engineering, Hefei University, Anhui 230022, China [2]Department of Chemistry, Jiangsu University, Jiangsu 212013, China |
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| 基金项目： | This work was supported by the Anhui Provincial Education Department （No. KJ2007A014） and Key Laboratory of Powder and Energy Materials of Hefei University |
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| 摘 要： | A novel cadmium coordination polymer [Cdls（OH）4（SO4）4（L1）6（L2）12]n （HL1 = 1,2,3-1H-triazole, HL2 = 5-methyl-lH-tetrazole） has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The compound crystallizes in cubicI-43d space group with a = 21.5247（4）, V = 9972.7（3） A3, Z = 4, Dc = 2.360 g/cm3, Mr = 3543.68, μ（MoKα） = 3.298 mm^-1, F（000） = 6696, the final R = 0.0340 and wR = 0.0992 for 1909 observed reflections （I 〉 2σ（I））. The compound contains two crystallographicatly independent Cd coordination centers linked up through one L1 and two L2 bridges. The structure displays an inorganic-organic hybrid cadmium coordination polymer.
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| 关 键 词： | 配位聚合物 晶体结构 俄亥俄州 四氮唑 二级 lH 高强度 单晶X射线衍射 |
Crystal Structure of a Novel Cadmium Coordination Polymer [Cd15（OH）4（SO4）4（L1）6（L2）12]n （HL1 = 1,2,3-1H-Triazole,HLe = 5-Methyl-lH-tetrazole |
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| ZHANG Quan-Zheng XIA Chang-Kun TIAN Chang-An LU Hong-Dian. Crystal Structure of a Novel Cadmium Coordination Polymer [Cd15（OH）4（SO4）4（L1）6（L2）12]n （HL1 = 1,2,3-1H-Triazole,HLe = 5-Methyl-lH-tetrazole[J]. Chinese Journal of Structural Chemistry, 2009, 28(9): 1167-1171 |
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| Authors: | ZHANG Quan-Zheng XIA Chang-Kun TIAN Chang-An LU Hong-Dian |
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| Abstract: | cadmium, crystal structure, coordination polymer |
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| Keywords: | cadmium crystal structure coordination polymer |
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